Product ID:FREON TF
MSDS Date:01/01/1985
FSC:6850
NIIN:00-319-0834
MSDS Number: BDWRZ

Emergency Phone: 502-582-1631

Cage: KO763

Cage: KO763

1,1,2-TRICHLORO-1,2,2-TRIFLUOROETHANE (FREON 113) (SARA

CAS: 76-13-1

RTECS: KJ4000000

OSHA PEL 1000PPM/1250STEL

ACGIH TLV: 1000PPM/1250STEL9192

LD50 LC50 Mixture:LD50, (ORAL) RATS 43,000 MG/KG (HMIS)
Health Hazards Acute and Chronic:EYES: MAY CAUSE CONJUNCTIVITUS. SKIN:
PROLONGED OR REPEATED CONTACT CAN CAUSE IRRITATION, DEFATTING OF
SKIN AND DERMATITIS. INHALATION: HIGH LEVELS CAN CAUSE CENTRAL
NERVOUS SYSTEM DEPRESSION, CARDIAC ARRYTHMIA. AT LOW
CONCENTRATIONS MAY CAUSE HEADACHE. INGESTION: LOW TO MODERATE
TOXICITY. (HMIS)
Effects of Overexposure:LT-HEADEDNESS, GIDDINESS, SHORT BREATH, POSS
NARCOSIS, POSS CARDIAC ARRHYTHMIAS @HI CONC.

First Aid:INH: REMOVE TO FRESH AIR, CALL MD. DO NOT GIVE EPINEPHRINE OR
SIMILAR DRUGS. SKIN/EYE CNTCT: FLUSH W/WATER.

Fire Fighting Procedures:KEEP CONTAINERS COOL WITH WATER SPRAY. WEAR
SELF-CONTAINED BREATHING APPARATUS. (HMIS)
Unusual Fire/Explosion Hazard:MAY DILUTE OR DISPLACE OXYGEN BELOW
LEVELS NECESSARY TO SUSTAIN LIFE. (HMIS)

Spill Release Procedures:VENT AREA, REMOVE OPEN FLAMES. [HMIS
INFORMATION-EVACUATE AREA. ABSORB SPILLED MATERIAL WITH AN INERT
MATERIAL. SHOVEL (SPARK PROOF) ABSORBENT MATERIAL INTO DRUMS AND
CLOSE. PROVIDE VENTILATION. REMOV E UNPROTECTED PERSONNEL. HMIS]

Handling and Storage Precautions:STORE CNTNRS IN CLEAN, DRY AREA. DO
NOT HEAT ABOVE 125F. [HMIS INFORMATION-AVOID BREATHING VAPORS.
VAPORS ARE HEAVY AND MAY ACCUMULATE. HMIS]
Other Precautions:[HMIS INFORMATION-PROTECT CONTAINERS FROM DAMAGE
DURING STORAGE. PREVENT LEAKAGE OR SPILLAGE WHICH MAY RESULT IN
OXYGEN DEPLETING BELOW LEVELS NECESSARY TO SUSTAIN LIFE. WHEN USED
INDOORS OR IN CONFIN ED SPACE USE A HALOCARBON DETECTOR.HMIS]

Respiratory Protection:USE AIR MASK IN HI CONC. [HMIS INFORMATION-AIR
CONCENTRATION OF 4500 PPM (0.45%0) IS NEARLY ODORLESS AND CAUSES
IMPAIRMENT OF MANUAL DEXTERITY AND VIGILANCE. HMIS]
Ventilation:LOCAL EXHST WHEN LG AMTS RELEASED, MECH IN LOW PLACES.
Protective Gloves:RUBBER
Eye Protection:SAFETY GOGGLES
Other Protective Equipment:WHEN USED INDOORS (IN CONFINED SPACES), IN
AMOUNTS GREATER THAN ONE CUP, USE HALOCARBON DETECTOR WITH
ALARM-HMIS
Supplemental Safety and Health
TYPE II OF MIL SPEC. [ HMIS INFORMATION-FREON 113 MAY DILUTE OR
DISPLACE OXYGEN BELOW LEVELS NECESSARY TO SUSTAIN LIFE.]HMIS HAS
ADDED ADDITIONAL SAFETY INFORMATION TO THIS MSDS AFTER A SERIOUS
EXPOSU RE WAS BROUGHT TO OUR ATTENTION. 1/6/95.

HCC:N1
Boiling Pt:B.P. Text:117.6F
Vapor Pres:334
Vapor Density:2.90
Spec Gravity:1.57
Evaporation Rate & Reference:0.3, CCL4
Solubility in Water:0.02% WT
Appearance and Odor:COLORLESS LIQ, SLIGHT
Percent Volatiles by Volume:100

Stability Indicator/Materials to Avoid:YES
ALKALI OR ALKALINE EARTH METALS, POWDERED AL, ZN, BE, ETC
Stability Condition to Avoid:OPEN FLAMES OR HI TEMP
Hazardous Decomposition Products:HCL & HF ACIDS, POSS PHOSGENE

Waste Disposal Methods:EVAPORATE OUTDOORS

Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.